Co-dimerisation of CO and a 1,3-diynyl-metal complex on an Ru3 cluster
Date
1996
Authors
Bruce, M.
Skelton, B.
White, A.
Zaitseva, N.
Editors
Advisors
Journal Title
Journal ISSN
Volume Title
Type:
Journal article
Citation
Journal- Chemical Society Dalton Transactions, 1996; 3151-3152(14):3151-3152
Statement of Responsibility
Michael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva
Conference Name
Abstract
The reaction of [W(CCCCH)(CO)3(cp)] with [Ru3{µ3HC2CC[W(CO)3(cp)]}(µ-CO)(CO)9(cp =-C5H5) afforded an unusual WRu3 cluster bearing a ligand formed by dimerisation of the diynyl ligand with incorporation of two molecules of CO, as shown by a crystal-structure determination.