Polymer networks of imine-crosslinked metal-organic cages: tuneable viscoelasticity and iodine adsorption
Date
2022
Authors
Schneider, M.L.
Campbell, J.A.
Slattery, A.D.
Bloch, W.M.
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Journal article
Citation
Chemical Communications, 2022; 58(86):12122-12125
Statement of Responsibility
Matthew L. Schneider, Jonathan A. Campbell, Ashley D. Slattery and Witold M. Bloch
Conference Name
Abstract
The solution-state structure of an amine-functionalised Cu24L24 cage (MOP-15) is elucidated, enabling its direct covalent crosslinking into a series of highly tuneable organogels. These soft porous networks exhibit up to a ∼10-fold increase in capacity for iodine compared to the discrete cage precursor.
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Published on 06 October 2022
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This journal is © The Royal Society of Chemistry 2022