3D hierarchical assembly of ultrathin MnO₂ nanoflakes on silicon nanowires for high performance micro-supercapacitors in Li- doped ionic liquid
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Date
2015
Authors
Dubal, D.
Aradilla, D.
Bidan, G.
Gentile, P.
Schubert, T.
Wimberg, J.
Sadki, S.
Gomez-Romero, P.
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Scientific Reports, 2015; 5(1):09771-1-09771-10
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Deepak P. Dubal, David Aradilla, Gérard Bidan, Pascal Gentile, Thomas J.S. Schubert, Jan Wimberg, Saïd Sadki, Pedro Gomez-Romero
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Abstract
Building of hierarchical core-shell hetero-structures is currently the subject of intensive research in the electrochemical field owing to its potential for making improved electrodes for high-performance micro-supercapacitors. Here we report a novel architecture design of hierarchical MnO₂@silicon nanowires (MnO₂@SiNWs) hetero-structures directly supported onto silicon wafer coupled with Liion doped 1-Methyl-1-propylpyrrolidinium bis(trifluromethylsulfonyl)imide (PMPyrrBTA) ionic liquids as electrolyte for micro-supercapacitors. A unique 3D mesoporous MnO₂@SiNWs in Li-ion doped IL electrolyte can be cycled reversibly across a voltage of 2.2 V and exhibits a high areal capacitance of 13 mFcm⁻². The high conductivity of the SiNWs arrays combined with the large surface area of ultrathin MnO₂ nanoflakes are responsible for the remarkable performance of these MnO₂@SiNWs hetero-structures which exhibit high energy density and excellent cycling stability. This combination of hybrid electrode and hybrid electrolyte opens up a novel avenue to design electrode materials for high-performance micro-supercapacitors.
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