Diffusion controlled vapour deposition of mixed doped PEDOT
Date
2018
Authors
Rudd, S.
Murphy, P.J.
Evans, D.R.
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Journal article
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Synthetic Metals, 2018; 242:61-66
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Abstract
Poly(3,4-ethylenedioxy thiophene) (PEDOT) displays many interesting properties from high electrical and thermal conduction to efficient electrocatalytic behaviour. Herein we report the vapour phase polymerization of PEDOT where ionic diffusion of two different doping anions in the oxidant layer during polymerisation is controlled, removing the need for ion exchange during post-processing. This one step process leads to PEDOTdoped with both to sylate and perchlorate, possessing properties not achievable using the individual anions,simple mixtures thereof, or other experimental pathways.
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Copyright 2018 Elsevier