Guest-induced crystal-to-crystal expansion and contraction of a 3-D porous coordination polymer

Date

2012

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Bloch, W.
Sumby, C.

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Chemical Communications, 2012; 48(19):2534-2536

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Witold M. Bloch and Christopher J. Sumby

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Abstract

A silver(I) 3-D porous coordination polymer (PCP, 1) with a sodalite topology undergoes a remarkable reversible crystal-to-crystal expansion and contraction upon exposure to different solvents. Notably, complete desolvation of 1 also facilitates a transformation to a non-porous 2-D coordination polymer (2).

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First published on the web 12 Jan 2012

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This journal is © The Royal Society of Chemistry

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