Regiospecific synthesis of bis(quinone monoacetals) and their annelation to give bisanthraquinones
Date
1987
Authors
Russell, R.A.
Day, A.I.
Pilley, B.A.
Leavy, P.J.
Warrener, R.N.
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Citation
Journal of the Chemical Society, Chemical Communications, 1987; 1987(21):1631-1633
Statement of Responsibility
Richard A. Russell, Anthony I. Day, Boyd A. Pilley, Peter J. Leavy and Ronald N. Warrener
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Abstract
The anodic oxidation of bis-(p-methoxyphenol) derivatives bearing methoxymethyl, methoxyethoxymethyl, or t-butyldimethylsilyl protecting groups affords regiospecifically bis-dienones which can be annelated with anions derived from 3-cyanophthalides to yield bisanthraquinones and bisanthracyclinones.
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