Five oxidation states in metal-bonded C4 chains
Date
1996
Authors
Bruce, M.
Denisovich, L.
Low, P.
Peregudova, S.
Ustynyuk, N.
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Journal article
Citation
Mendeleev Communications, 1996; 6(5):200-201
Statement of Responsibility
Michael I. Bruce, Larisa I. Denisovich, Paul J. Low, Svetlana M. Peregudova and Nikolai A. Ustynyuk
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Abstract
The 36-electron diruthenium buta-l,3-diynyl complexes [Ru]C triple bond; length of mdash C–C triple bond; length of mdash C[Ru] [Ru = Ru(PPh3)2Cp and Ru(PMe3)(PPh3)Cp] undergo four stepwise one-electron oxidation–reduction processes by cyclic voltammetry; some of the oxidised complexes have also been prepared by chemical oxidation.
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