Synthesis of sulfur-containing aryl and heteroaryl vinyls via Suzuki–Miyaura cross-coupling for the preparation of SERS-active polymers
Date
2009
Authors
Perez-Pineiroa, R.
Dai, S.
Alvarez-Puebla, R.
Wigginton, J.
Al-Hourani, B.
Fenniri, H.
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Journal article
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Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry, 2009; 50(39):5467-5469
Statement of Responsibility
Rolando Perez-Pineiro, Sheng Dai, Ramon Alvarez-Puebla, James Wigginton, Baker Jawabrah Al-Hourani and Hicham Fenniri
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Abstract
The preparation of sulfur-containing aryl and heteroaryl vinyl co-monomers via Suzuki–Miyaura cross-coupling between the corresponding mercaptomethyl arylboronates and in situ-generated vinyl bromides is described. Surface-enhanced Raman scattering (SERS) studies of the target compounds on gold nanoparticles confirmed their potential as spectroscopic tags in the fabrication of SERS-encoded polymers for combinatorial screening and biomedical diagnostics.
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© 2009 Elsevier Ltd. All rights reserved.