Catalytic polymerization of anthracene in a recyclable SBA-15 reactor with high iron content by a Friedel–Crafts alkylation
Date
2012
Authors
Kim, J.
Anand, C.
Talapaneni, S.N.
You, J.
Aldeyab, S.S.
Kim, E.
Vinu, A.
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Advisors
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Journal article
Citation
Angewandte Chemie International Edition, 2012; 51(12):2859-2863
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Abstract
Ironing it out: A FeSBA-15 catalyst with a high iron content as well as a large pore diameter has been synthesized and used for the production of soluble poly(methylene anthracene) (PMAn, see scheme). The catalyst is stable, active, reusable, and affords a high yield of high-molecular-weight PMAn. The properties of the PMAns obtained can be controlled by tuning the specific surface area, pore diameter, pore volume, and Fe content of the catalysts.
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Data source: Supporting information, http://api.onlinelibrary.wiley.com/asset/v1/doi/10.1002%2Fanie.201107145/asset/supinfo%2Fanie_201107145_sm_miscellaneous_information.pdf?l=SkaBT8QEx2qMKFzmpntImo4uJYL74sHXQ%2BFtVtC%2BKB762lO0nodkqF0CuLmuYiMP2MRZhBgChT9E%0AEEEf2I0q%2FHYI%2BZkF0C%2FwvwuDlaPf0pDa1YdV2utbow%3D%3D
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Copyright 2012 Wiley-VCH