Attenuation of reactivity by product solvation: synthesis and molecular structure of [K{(η⁶-Mes)NC(H)N(Mes)}{(η⁶-Mes)NHC(H)N(Mes)], the first formamidinate complex of potassium

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dc.contributor.authorBaldamus, Jensen
dc.contributor.authorBerghof, Christianeen
dc.contributor.authorCole, Marcus Lawforden
dc.contributor.authorEvans, David J.en
dc.contributor.authorHey-Hawkins, Evamarieen
dc.contributor.authorJunk, Peter C.en
dc.contributor.schoolSchool of Chemistry and Physicsen
dc.date.issued2002en
dc.description© Royal Society of Chemistry 2008en
dc.description.abstractAmbient temperature treatment of the new bulky formamidine (2,4,6-Me₃C₆H₂)NC(H)NH(2,4,6-Me₃C₆H₂), HFMes, with 0.5 or 1.0 equivalents of potassium hydride or potassium bis(trimethylsilyl)amide yields the first potassium formamidinate complex [K{(η⁶-Mes)NC(H)N(Mes)}{(η⁶-Mes)NHC(H)N(Mes)], which displays attenuated reactivity with respect to deprotonation and solvent replacement of the included HFMes ligand.en
dc.description.statementofresponsibilityJens Baldamus, Christiane Berghof, Marcus L. Cole, David J. Evans, Evamarie Hey-Hawkins and Peter Cen
dc.identifier.citationDalton Transactions, 2002; 14:2802-2804en
dc.identifier.doi10.1039/b204224jen
dc.identifier.issn1477-9226en
dc.identifier.urihttp://hdl.handle.net/2440/34920
dc.language.isoenen
dc.publisherRoyal Society Chemistryen
dc.source.urihttp://www.rsc.org/publishing/journals/DT/article.asp?doi=b204224jen
dc.titleAttenuation of reactivity by product solvation: synthesis and molecular structure of [K{(η⁶-Mes)NC(H)N(Mes)}{(η⁶-Mes)NHC(H)N(Mes)], the first formamidinate complex of potassiumen
dc.title.alternativeAttenuation of reactivity by product solvation: synthesis and molecular structure of [K{(eta(6)-Mes)NC(H)N(Mes)}{(eta(6)-Mes)NHC(H)N(Mes)], the first formamidinate complex of potassiumen
dc.typeJournal articleen

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