Antifogging Surface Facilitated by Nanoscale Coatings with Controllable Hydrophobicity and Cross-Linking Density
Date
2017
Authors
Nam, E.
Wong, E.H.H.
Tan, S.
Fu, Q.
Blencowe, A.
Qiao, G.G.
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Journal article
Citation
Macromolecular Materials and Engineering, 2017; 302(1)
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Abstract
Antifogging and frost-resistant coatings can be used in a wide range of applications and enable high light transmission through substrates even under changes in environmental conditions. In this study, surface confined and cross-linked antifogging thin films are fabricated on glass slides via catalyst induced cross-linking (CIC), which has been recently introduced as an easy and efficient cross-linking methodology. Four different poly(ethylene glycol) (PEG)-based polymers with different hydrophilicity are synthesized and used to prepare films via CIC. Films prepared from the most hydrophilic PEG-based polymers display the best antifogging performances when exposed to a temperature change from -20 to 22 °C. Furthermore, several parameters including cross-linking density, surface roughness, hydrophobicity, and exposure time are also evaluated in terms of film transparency. Through these measurements, it is determined that, more loosely cross-linked films retain antifogging ability for longer time periods due to higher film swellability as compared to, more highly cross-linked films. This study signifies the crucial role of the film cross-linking density and hydrophilicity on the antifogging function.
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Dissertation Note
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Link to a related website: https://rss.onlinelibrary.wiley.com/doi/am-pdf/10.1002/mame.201600199, Open Access via Unpaywall
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Copyright 2016 Wiley