Nano-to-macroscale poly(methyl methacrylate) stereocomplex assemblies

Date

2009

Authors

Goh, T.K.
Tan, J.F.
Guntari, S.N.
Satoh, K.
Blencowe, A.
Kamigaito, M.
Qiao, G.G.

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Angewandte Chemie International Edition, 2009; 48(46):8707-8711

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Abstract

We can do so much together: The stereocomplexation of complementary strands of stereoregular poly(methyl methacrylate) (PMMA) to form triple-stranded helices led to a fascinating array of PMMA stereocomplex morphologies. The different polymer-helix assemblies were constructed from a single set of complementary polymers (syndiotactic (blue in the picture) and isotactic PMMA (orange)) by simple tuning of the mixing ratio and concentration.

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Copyright 2009 Wiley-VCH Verlag

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