Biosynthetically-inspired oxidations of capillobenzopyranol

dc.contributor.author	Pepper, H.
dc.contributor.author	Lam, H.
dc.contributor.author	George, J.
dc.date.issued	2017
dc.description.abstract	The synthesis of verrubenzospirolactone from its proposed biosynthetic precursor, capillobenzopyranol, has been shown to be chemically feasible via a simple reaction sequence. The key steps are a chemoselective furan oxidation mediated by NaClO₂, a stereoselective dehydration of a γ-methoxybutenolide, and an intramolecular Diels-Alder reaction.
dc.description.statementofresponsibility	Henry P. Pepper, Hiu C. Lam and Jonathan H. George
dc.identifier.citation	Organic and Biomolecular Chemistry, 2017; 15(22):4811-4815
dc.identifier.doi	10.1039/c7ob00868f
dc.identifier.issn	1477-0520
dc.identifier.issn	1477-0539
dc.identifier.orcid	George, J. [0000-0002-7330-2160]
dc.identifier.uri	http://hdl.handle.net/2440/106799
dc.language.iso	en
dc.publisher	Royal Society of Chemistry
dc.relation.grant	http://purl.org/au-research/grants/arc/DP160103393
dc.rights	This journal is © The Royal Society of Chemistry 2017
dc.source.uri	https://doi.org/10.1039/c7ob00868f
dc.title	Biosynthetically-inspired oxidations of capillobenzopyranol
dc.type	Journal article
pubs.publication-status	Published

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