Network structures of cyclotriveratrylene and its derivatives
Date
2005
Authors
Hardie, M.
Ahmad, R.
Sumby, C.
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Journal article
Citation
New Journal of Chemistry: a journal for new directions in chemistry, 2005; 29(10):1231-1240
Statement of Responsibility
Michaele J. Hardie, Ruksanna Ahmad and Christopher J. Sumby
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DOI
Abstract
The host molecule cyclotriveratrylene can be incorporated into network structures by acting as a hydrogen bond acceptor or as a chelating ligand for Group 1 metals. New CTV-based ligands with pyridyl functional groups have been synthesised for use as multifunctional ligands in coordination networks. Resultant hydrogen bonded network structures and coordination networks show a range of chain, 2-D and 3-D structures with hexagonal 6³ nets predominating. Recent results are discussed including highly complex 3-D networks where the molecular hosts pack in a tetrameric back-to-back fashion.
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© Royal Society of Chemistry 2005