Basu Baul, T.Dahr, S.Kharbani, N.Pyke, S.Butcher, R.Smith, F.2007-02-252007-02-251999Main Group Metal Chemistry, 1999; 22(7):413-4210792-12412191-0219http://hdl.handle.net/2440/4757Three new triorganotin(IV) complexes, the trimethyl, tributyl and triphenyl derivatives of 5-(4-chlorophenylazo)salicylic acid, have been synthesised and characterised by <sup>1</sup>H, <sup>13</sup>C, <sup>119</sup>Sn NMR, IR and elemental analysis and the crystal structure of triphenyltin-5-(4-chlorophenylazo)salicylate is reported. The crystals are monoclinic, space group P2 <inf>1</inf>/n with a = 9.566(1) Å, b = 14.550(2)Å, c = 22.528(3)Å, β= 94.04(1), V= 3127.8(7) Å <sup>S</sup>, Z = 4 and D <inf>calc</inf> = 1.42 Mg.m <sup>-3</sup>. There is an encapsulated molecule of hexane incorporated in the structure. This complex adopts a monomeric distorted tetrahedral configuration with the ligand coordinated via a carboxylate oxygen.enSynthesis and structural characterization of some triorganotin(IV) complexes of 5-(4-chlorophenulazo)salicylic acid: Crystal and molecular structure of triphenyltin 5-(4-chlorophenylazo)salicylate 0.5C₆H₁₄Synthesis and structural characterization of some triorganotin(IV) complexes of 5-(4-chlorophenulazo)salicylic acid: Crystal and molecular structure of triphenyltin 5-(4-chlorophenylazo)salicylate 0.5C(6)H(14)Journal article003000275010.1515/MGMC.1999.22.7.4130000816463000012-s2.0-003773451066756Pyke, S. [0000-0002-0061-5115]