Markwell-Heys, A.W.Schneider, M.L.Madridejos, J.M.L.Metha, G.F.Bloch, W.M.2021-06-182021-06-182021Chemical Communications, 2021; 57(23):2915-29181359-73451364-548Xhttp://hdl.handle.net/2440/130796We report the self-sorting of a dynamic combinatorial library (DCL) of metal–organic cages composed of a rotationally isomerisable ligand. Convergence of the DCL occurs upon crystallisation and leads to low-symmetry Cu₄L₂L′₂ cages that display differing porosities based on their overall shape and ligand configuration.enThis journal is © The Royal Society of Chemistry 2021.Self-sorting of porous Cu₄L₂L′₂ metal–organic cages composed of isomerisable ligandsSelf-sorting of porous Cu(4)L(2)L'(2) metal-organic cages composed of isomerisable ligandsJournal article100003589910.1039/d0cc08076d0006301348000152-s2.0-85102739652567325Schneider, M.L. [0000-0001-9445-2427]Metha, G.F. [0000-0003-1094-0947]Bloch, W.M. [0000-0003-1084-1287]