Fan, Q.Jiang, J.Zhang, S.Zhou, T.Pang, W.K.Gu, Q.Liu, H.Guo, Z.Wang, J.2021-07-292021-07-292021Advanced Energy Materials, 2021; 11(32):2100957-1-2100957-121614-68321614-6840http://hdl.handle.net/2440/131363First published: 26 June 2021Challenges from the insulating S and Li2S2/Li2S (Li2S1–2) discharge products are restricting the development of the high-energy-density Li–S battery system. The deposition of insulating Li2S1–2 on the surfaces of S based cathodes (e.g., S and Li2S) limits the reaction kinetics, leading to inferior electrochemical performance. In this work, the impact of binders on the deposition of Li2S1–2 on S based cathodes is revealed, along with the interaction between polyvinylidene difluoride and Li2S/polysulfides. This interaction can obstruct the electrochemical reactions near the binder, leading to dense deposition of insulating Li2S1–2 that covers the cathode surface. Without such a binder, localized and uniform Li2S1–2 deposition throughout the whole cathode can be achieved, effectively avoiding surface blockage and significantly improving electrode utilization. A full battery constructed with a binder-free Li2S cathode delivers a gravimetric and volumetric energy density of 331.0 Wh kg−1 and 281.5 Wh L−1, under ultrahigh Li2S loading (16.2 mgLi2S cm−2) with lean electrolyte (2.0 µL mgLi2S−1), providing a facile but practical approach to the design of next-generation S-based batteries.en© 2021 Wiley-VCH GmbHHhigh energy densities, Li2S2 /Li2S deposition, Li–S batteries; lithium sulfide cathodes; polyvinylidene difluoridesJournal article100004330910.1002/aenm.2021009570006665984000012-s2.0-85108792919580258Zhang, S. [0000-0002-3268-5708]Guo, Z. [0000-0003-3464-5301]