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https://hdl.handle.net/2440/34958
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DC Field | Value | Language |
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dc.contributor.author | Zhang, T. | - |
dc.contributor.author | Lee, Y. | - |
dc.contributor.author | Kee, T. | - |
dc.contributor.author | Barbara, P. | - |
dc.date.issued | 2005 | - |
dc.identifier.citation | Chemical Physics Letters, 2005; 403(4-6):257-261 | - |
dc.identifier.issn | 0009-2614 | - |
dc.identifier.issn | 1873-4448 | - |
dc.identifier.uri | http://hdl.handle.net/2440/34958 | - |
dc.description.abstract | Electron-cation geminate recombination in isooctane has been reinvestigated by femtosecond spectroscopy. The observed recombination kinetics are well-fit by a single exponential decay (τ = 400 ± 40 fs) and exhibit a significant hydrogen/deuterium kinetic isotope effect. The kinetics are not affected by varying the incident intensity or by exciting the recombining electrons with a high power 800 nm pulse. These observations strongly suggest that the recombination rate is not limited by diffusive motion of the ions to form a contact ion pair, but rather by the electron transfer reaction rate between the ions in a contact ion pair. © 2005 Elsevier B.V. All rights reserved. | - |
dc.description.statementofresponsibility | Tieqiao Zhang, Young Jong Lee, Tak W. Kee and Paul F. Barbara | - |
dc.description.uri | http://www.elsevier.com/wps/find/journaldescription.cws_home/505707/description#description | - |
dc.language.iso | en | - |
dc.publisher | Elsevier Science BV | - |
dc.source.uri | http://dx.doi.org/10.1016/j.cplett.2005.01.015 | - |
dc.title | The mechanism of electron-cation geminate recombination in liquid isooctane | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1016/j.cplett.2005.01.015 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Kee, T. [0000-0002-4907-4663] | - |
Appears in Collections: | Aurora harvest Environment Institute publications Physics publications |
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