Environment Institute

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Browsing Environment Institute by Author "Abat, M."

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    Adsorption and desorption of copper and zinc in tropical peat soils of Sarawak, Malaysia
    (Elsevier Science BV, 2012) Abat, M.; McLaughlin, M.; Kirby, J.; Stacey, S.
    Tropical peat soils are inherently deficient in micronutrients particularly copper (Cu) and zinc (Zn). In addition, limited information is available on the adsorption and desorption of these micronutrients in these soils, which are important factors governing nutrient concentration in the soil solution and nutrient availability to plants. A study was carried out to quantify adsorption and desorption of Cu and Zn in three untreated and limed tropical peat soils of Sarawak, Malaysia. Copper and Zn adsorption increased gradually with increasing levels of added Cu and Zn in both control and limed soils. The adsorption of Cu and Zn in limed soils increased by 50 and 67 fold, respectively, relative to control soils. The Freundlich constant (K F) values for Cu in both control and limed peat soils were higher than for Zn indicating that Cu is more strongly adsorbed to the soil solid phase than Zn. The K F values for Cu and Zn in this study were higher than those reported for other soil types. The percentage of adsorbed Cu and Zn susceptible to desorption into 5mM DTPA was higher than that desorbed by 10mM Ca(NO 3) 2 in all soils. A higher percentage of Cu than that of Zn was desorbed by DTPA because Cu has a higher critical stability constant with DTPA. Liming is necessary to increase the pH of peat soils but it also inevitably decreases the solubility and hence the bioavailability of Cu and Zn. This study provides evidence on the importance of adsorption and desorption data for estimating nutrient availability for plant uptake in tropical peat soils. © 2012 Elsevier B.V.
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    Responses of tomato var. Tiny Tom to application of copper and zinc fertilizers in three limed tropical peat soils of Sarawak
    (Marcel Dekker Inc, 2013) Abat, M.; McLaughlin, M.; Stacey, S.; Kirby, J.
    We assessed the response of the tomato variety “Tiny Tom” to the application of copper (Cu) and zinc (Zn) fertilizers in three tropical peat soils of Sarawak: mixed swamp forest, Alan forest and Padang Alan forest. Limed soils were used because peat soils in their natural condition are unsuitable to sustain healthy growth of most crops. Yield responses were correlated with added Cu and Zn using Mitscherlich model. Adequate levels of applied Cu and Zn were calculated as those which resulted in 90% of the maximum obtainable shoot dry weight. Application of Cu and Zn significantly(P ≤ 0.05) increased the shoot dry weight and the shoot Cu and Zn concentrations of tomato. Application of the equivalent of 8.3 kg Cu and 5.2 kg Zn per ha was required to achieve 90% of the maximum shoot dry weight. In tomato shoots, the critical concentration for Cu was 18 mg/kg and for Zn, 92 mg/kg. The corresponding concentrations for diethylenetriaminepentaaceticacid (DTPA) extractable Cu and Zn in the soils were 2.3 mg Cu kg−1 and 3.6 mg Zn kg−1. However, the addition of Cu fertilizer also increased Zn uptake by tomato plant, probably by displacing native Zn that was weakly sorbed to the soil solid phase.