University Administration

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Browsing University Administration by Author "Albuquerque, I."

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    ItemOpen Access
    Laying waste to mercury: inexpensive sorbents made from sulfur and recycled cooking oils
    (Wiley, 2017) Worthington, M.; Kucera, R.; Albuquerque, I.; Gibson, C.; Sibley, A.; Slattery, A.; Campbell, J.; Alboaiji, S.; Muller, K.; Young, J.; Adamson, N.; Gascooke, J.; Jampaiah, D.; Sabri, Y.; Bhargava, S.; Ippolito, S.; Lewis, D.; Quinton, J.; Ellis, A.; Johs, A.; et al.
    Mercury pollution threatens the environment and human health across the globe. This neurotoxic substance is encountered in artisanal gold mining, coal combustion, oil and gas refining, waste incineration, chloralkali plant operation, metallurgy, and areas of agriculture in which mercury-rich fungicides are used. Thousands of tonnes of mercury are emitted annually through these activities. With the Minamata Convention on Mercury entering force this year, increasing regulation of mercury pollution is imminent. It is therefore critical to provide inexpensive and scalable mercury sorbents. The research herein addresses this need by introducing low-cost mercury sorbents made solely from sulfur and unsaturated cooking oils. A porous version of the polymer was prepared by simply synthesising the polymer in the presence of a sodium chloride porogen. The resulting material is a rubber that captures liquid mercury metal, mercury vapour, inorganic mercury bound to organic matter, and highly toxic alkylmercury compounds. Mercury removal from air, water and soil was demonstrated. Because sulfur is a by-product of petroleum refining and spent cooking oils from the food industry are suitable starting materials, these mercury-capturing polymers can be synthesised entirely from waste and supplied on multi-kilogram scales. This study is therefore an advance in waste valorisation and environmental chemistry.
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    ItemOpen Access
    Sulfur-limonene polysulfide: a material synthesized entirely from industrial by-products and its use in removing toxic metals from water and soil
    (Wiley, 2016) Crockett, M.; Evans, A.; Worthington, M.; Albuquerque, I.; Slattery, A.; Gibson, C.; Campbell, J.; Lewis, D.; Bernardes, G.; Chalker, J.
    A polysulfide material was synthesized by the direct reaction of sulfur and d-limonene, by-products of the petroleum and citrus industries, respectively. The resulting material was processed into functional coatings or molded into solid devices for the removal of palladium and mercury salts from water and soil. The binding of mercury(II) to the sulfur-limonene polysulfide resulted in a color change. These properties motivate application in next-generation environmental remediation and mercury sensing.