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https://hdl.handle.net/2440/104993
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dc.contributor.author | Stassen, I. | - |
dc.contributor.author | Styles, M. | - |
dc.contributor.author | Van Assche, T. | - |
dc.contributor.author | Campagnol, N. | - |
dc.contributor.author | Fransaer, J. | - |
dc.contributor.author | Denayer, J. | - |
dc.contributor.author | Tan, J. | - |
dc.contributor.author | Falcaro, P. | - |
dc.contributor.author | De Vos, D. | - |
dc.contributor.author | Ameloot, R. | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | Chemistry of Materials, 2015; 27(5):1801-1807 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.issn | 1520-5002 | - |
dc.identifier.uri | http://hdl.handle.net/2440/104993 | - |
dc.description.abstract | Film deposition is an enabling technology for integration of novel functional materials into real-world practical applications. We report both the anodic and cathodic electrochemical film deposition of UiO-66, a prototype of highly stable, zirconium-based metal−organic frameworks, using zirconium foil as the only metal source. The fundamentally different film formation mechanisms at the cathode and anode result in a significantly different coating adhesion strength, mainly due to the formation of an oxide film serving as a bridging layer at the anode. The patterned deposition capability of the electrochemical method enables the straightforward integration of UiO-66 as a sorbent film in a miniaturized sorbent trap for online analytical sampling and concentration of dilute volatile organic compounds. | - |
dc.description.statementofresponsibility | Ivo Stassen, Mark Styles, Tom Van Assche, Nicolò Campagnol, Jan Fransaer, Joeri Denayer, Jin-Chong Tan, Paolo Falcaro, Dirk De Vos and Rob Ameloot | - |
dc.language.iso | en | - |
dc.publisher | American Chemical Society | - |
dc.rights | © 2015 American Chemical Society | - |
dc.source.uri | http://dx.doi.org/10.1021/cm504806p | - |
dc.title | Electrochemical film deposition of the zirconium metal-organic framework uio-66 and application in a miniaturized sorbent trap | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1021/cm504806p | - |
pubs.publication-status | Published | - |
Appears in Collections: | Aurora harvest 3 Chemical Engineering publications |
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