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https://hdl.handle.net/2440/105562
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Type: | Journal article |
Title: | A biomimetic synthetic approach to the frondosins |
Author: | Kuan, K. Hirschvogel, A. George, J. |
Citation: | Australian Journal of Chemistry: an international journal for chemical science, 2016; 69(12):1420-1423 |
Publisher: | CSIRO Publishing |
Issue Date: | 2016 |
ISSN: | 0004-9425 1445-0038 |
Statement of Responsibility: | Kevin K. W. Kuan, Aylin M. C. Hirschvogel and Jonathan H. George |
Abstract: | The frondosins are a family of five marine sponge-derived meroterpenoids. We propose that the 6-7 ring system common to each of the frondosins is biosynthesized via ring expansion of a 6–6 ring system. Compelling evidence in favour of this proposal was obtained in the form of a biomimetic synthesis of the frondosin 6–7 ring system, which features a highly stereo- and regio-selective ring expansion cascade reaction as the key step. |
Rights: | Journal compilation © CSIRO 2016 |
DOI: | 10.1071/CH16218 |
Grant ID: | http://purl.org/au-research/grants/arc/DP160103393 |
Published version: | http://dx.doi.org/10.1071/ch16218 |
Appears in Collections: | Aurora harvest 3 Chemistry publications |
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