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https://hdl.handle.net/2440/114381
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Type: | Journal article |
Title: | Aggregation behavior of ligand-protected Au₉ clusters on sputtered atomic layer deposition TiO₂ |
Other Titles: | Aggregation behavior of ligand-protected Au(9) clusters on sputtered atomic layer deposition TiO(2) |
Author: | Al Qahtani, H. Metha, G. Walsh, R. Golovko, V. Andersson, G. Nakayama, T. |
Citation: | The Journal of Physical Chemistry C: Energy Conversion and Storage, Optical and Electronic Devices, Interfaces, Nanomaterials, and Hard Matter, 2017; 121(20):10781-10789 |
Publisher: | American Chemical Society |
Issue Date: | 2017 |
ISSN: | 1932-7447 1932-7455 |
Statement of Responsibility: | Hassan S. Al Qahtani, Gregory F. Metha, Rick B. Walsh, Vladimir B. Golovko, Gunther G. Andersson, and Tomonobu Nakayama |
Abstract: | [Au₉(PPh₃)₈)](NO₃)₃ (Au)₉ clusters were deposited onto sputtered ALD titania surfaces. Atomic force microscopy (AFM) was used to determine the height and distributions of the Au₉ clusters over the titania surface fabricated using atomic layer deposition (ALD). Synchrotron X-ray photoelectron spectroscopy (XPS) was used to derive information about the degree of agglomeration of the Au₉ clusters due to the annealing process. Both AFM and XPS show that the Au₉ clusters deposited on ALD titania are partially agglomerated after annealing. Deposition of the [Au₉(PPh₃)₈)](NO₃)₃ clusters on sputtered ALD titania is compared with deposition of the same cluster on titania nanosheets of previous work. |
Rights: | © 2017 American Chemical Society |
DOI: | 10.1021/acs.jpcc.6b11590 |
Published version: | http://dx.doi.org/10.1021/acs.jpcc.6b11590 |
Appears in Collections: | Aurora harvest 8 Chemistry publications |
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