Adelaide Research & Scholarship
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https://hdl.handle.net/2440/124648
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| Type: | Journal article |
| Title: | Boronate Ester Bullvalenes |
| Author: | Patel, H.D. Tran, T.-H. Sumby, C.J. Pašteka, L.F. Fallon, T. |
| Citation: | Journal of the American Chemical Society, 2020; 142(8):3680-3685 |
| Publisher: | American Chemical Society |
| Issue Date: | 2020 |
| ISSN: | 0002-7863 1520-5126 |
| Statement of Responsibility: | Harshal D. Patel, Thanh-Huyen Tran, Christopher J. Sumby, Lukáš F. Pašteka, Thomas Fallon |
| Abstract: | Boronate ester bullvalenes are now accessible in two to four operationally simple steps. This unlocks late-stage diversification through Suzuki cross-coupling reactions to give mono-, di-, and trisubstituted bullvalenes. Moreover, a linchpin strategy enables preprogrammed installation of two different substituents. Analysis of solution phase isomer distributions and single-crystal X-ray structures reveals that isomer preference in the crystal lattice is due to general shape selectivity. |
| Rights: | © 2020 American Chemical Society |
| DOI: | 10.1021/jacs.9b12930 |
| Grant ID: | http://purl.org/au-research/grants/arc/LE0989336 |
| Published version: | http://dx.doi.org/10.1021/jacs.9b12930 |
| Appears in Collections: | Aurora harvest 8 Chemistry publications |
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