Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/125025
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Type: Journal article
Title: Automatic segmentation of multiple structures in knee arthroscopy using deep learning
Author: Jonmohamadi, Y.
Takeda, Y.
Liu, F.
Sasazawa, F.
Maicas, G.
Crawford, R.
Roberts, J.
Pandey, A.
Carneiro, G.
Citation: IEEE Access, 2020; 8:51853-51861
Publisher: Royal Society of Chemistry
Issue Date: 2020
ISSN: 2169-3536
2169-3536
Statement of
Responsibility: 
Hussein Rasool Abid, Zana Hassan Rada, Yuan Li, Hussein A. Mohammed, Yuan Wang, Shaobin Wang, Hamidreza Arandiyan, Xiaoyao Tan and Shaomin Liu
Abstract: Aluminum trimesate-based MOF (MIL-96-(Al)) has attracted intense attention due to its high chemical stability and strong CO2 adsorption capacity. In this study, CO2 capture and selectivity of MIL-96-Al was further improved by the coordination of the second metal Ca. To this end, a series of MIL-96(Al)–Ca were hydrothermally synthesised by a one-pot method, varying the molar ratio of Ca2+/Al3+. It is shown that the variation of Ca2+/Al3+ ratio results in significant changes in crystal shape and size. The shape varies from the hexagonal rods capped in the ends by a hexagonal pyramid in MIL-96(Al) without Ca to the thin hexagonal disks in MIL-96(Al)–Ca4 (the highest Ca content). Adsorption studies reveal that the CO2 adsorption on MIL-96(Al)–Ca1 and MIL-96(Al)–Ca2 at pressures up to 950 kPa is vastly improved due to the enhanced pore volumes compared to MIL-96(Al). The CO2 uptake on these materials measured in the above sequence is 10.22, 9.38 and 8.09 mmol g−1, respectively. However, the CO2 uptake reduces to 5.26 mmol g−1 on MIL-96(Al)–Ca4. Compared with MIL-96(Al)–Ca1, the N2 adsorption in MIL-96(Al)–Ca4 is significantly reduced by 90% at similar operational conditions. At 100 and 28.8 kPa, the selectivity of MIL-96(Al)–Ca4 to CO2/N2 reaches up to 67 and 841.42, respectively, which is equivalent to 5 and 26 times the selectivity of MIL-96(Al). The present findings highlight that MIL-96(Al) with second metal Ca coordination is a potential candidate as an alternative CO2 adsorbent for practical applications.
Rights: Open Access Article. Published on 25 February 2020. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
RMID: 1000018355
DOI: 10.1109/ACCESS.2020.2980025
Grant ID: http://purl.org/au-research/grants/arc/DP170104264
Appears in Collections:Chemical Engineering publications

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