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https://hdl.handle.net/2440/125048
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Type: | Journal article |
Title: | Porous metal-porphyrin triazine-based frameworks for efficient CO₂ electroreduction |
Other Titles: | Porous metal-porphyrin triazine-based frameworks for efficient CO2 electroreduction |
Author: | Feng, S. Zheng, W. Zhu, J. Li, Z. Yang, B. Wen, Z. Lu, J. Lei, L. Wang, S. Hou, Y. |
Citation: | Applied Catalysis B: Environmental, 2020; 270:118908-1-118908-8 |
Publisher: | Elsevier |
Issue Date: | 2020 |
ISSN: | 0926-3373 1873-3883 |
Statement of Responsibility: | Shaohua Feng, Wanzhen Zheng, Jingke Zhu, Zhongjian Li, Bin Yang, Zhenhai Wen, Jianguo Lu, Lecheng Lei, Shaobin Wang, Yang Hou |
Abstract: | Electrochemical reduction of CO₂ (ECR-CO₂) into high value-added products plays a crucial role in energy conversions. Herein, we developed a family of porous metal-porphyrin triazine-based frameworks (MPTFs-x, M = Mn, Fe, Co, Ni, and Cu, x = temperature) with a specific surface area up to 977 m² g⁻¹ and homogenously dispersed transition-metals. Benefiting from a high content of N species of 8.43 at.% and abundantly exposed Ni-Nₓ active sites, NiPTFs-600 displayed a superb Faradaic efficiency (FE) of CO production (>90 %) in the range of −0.55 V to −0.95 V with the maximum FE of 97.6 % and current density of 10.8 mA cm⁻² at −0.8 V. The reaction mechanism was found to be the adsorption of CO₂ molecules to form *CO₂ intermediates, accompanied by successive protonation to produce *COOH and then *CO |
Keywords: | Porous metal-porphyrin triazine-based frameworks; electrocatalysis; CO₂ reduction reaction; CO production |
Rights: | © 2020 Elsevier B.V. All rights reserved. |
DOI: | 10.1016/j.apcatb.2020.118908 |
Grant ID: | http://purl.org/au-research/grants/arc/DP170104264 |
Published version: | http://dx.doi.org/10.1016/j.apcatb.2020.118908 |
Appears in Collections: | Aurora harvest 4 Chemical Engineering publications |
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