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Type: Journal article
Title: Biomimetic total synthesis of the rubiginosin meroterpenoids
Author: Burchill, L.
Day, A.J.
Yahiaoui, O.
George, J.H.
Citation: Organic Letters, 2021; 23(2):578-582
Publisher: American Chemical Society
Issue Date: 2021
ISSN: 1523-7060
Statement of
Laura Burchill, Aaron J. Day, Oussama Yahiaoui, and Jonathan H. George
Abstract: Total synthesis of the <i>Rhododendron</i> meroterpenoids rubiginosins A and G, which both contain unusual 6-6-6-4 ring systems, has been achieved using a bioinspired cascade approach. Stepwise synthesis of these natural products, and the related 6-6-5-4 meroterpenoids fastinoid B and rhodonoid B, from naturally occurring chromene precursors is also reported.
Keywords: Rhododendron
Biological Products
Molecular Structure
Rights: © 2020 American Chemical Society
DOI: 10.1021/acs.orglett.0c04117
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