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https://hdl.handle.net/2440/139944
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Type: | Journal article |
Title: | 2D MoN₁.₂rGO Stacked Heterostructures Enabled Water State Modification for Highly Efficient Interfacial Solar Evaporation |
Other Titles: | 2D MoN1.2rGO Stacked Heterostructures Enabled Water State Modification for Highly Efficient Interfacial Solar Evaporation |
Author: | Yu, H. Wang, D. Jin, H. Wu, P. Wu, X. Chu, D. Lu, Y. Yang, X. Xu, H. |
Citation: | Advanced Functional Materials, 2023; 33(24):1-9 |
Publisher: | Wiley-VCH |
Issue Date: | 2023 |
ISSN: | 1616-301X 1616-3028 |
Statement of Responsibility: | Huimin Yu, Deyu Wang, Huanyu Jin, Pan Wu, Xuan Wu, Dewei Chu, Yi Lu, Xiaofei Yang, and Haolan Xu |
Abstract: | Improving interfacial solar evaporation performance is crucial for the practical application of this technology in solar-driven seawater desalination. Lowering evaporation enthalpy is one of the most promising and effective strategies to significantly improve solar evaporation rate. In this study, a new pathway to lower vaporization enthalpy by introducing heterogeneous interactions between hydrophilic hybrid materials and water molecules is developed. 2D MoN₁.₂ nanosheets are synthesized and integrated with rGO nanosheets to form stacked MoN₁.₂-rGO heterostructures with massive junction interfaces for interfacial solar evaporation. Molecular dynamics simulation confirms that atomic thick 2D MoN₁.₂ and rGO in the MoN₁.₂-rGO heterostructures simultaneously interact with water molecules, while the interactions are remarkably different. These heterogeneous interactions cause an imbalanced water state, which easily breaks the hydrogen bonds between water molecules, leading to dramatically lowered vaporization enthalpy and improved solar evaporation rate (2.6 kg m⁻²h⁻¹). This study provides a promising strategy for designing 2D-2D heterostructures to regulate evaporation enthalpy to improve solar evaporate rate for clean water production. |
Keywords: | 2D heterostructures; evaporation enthalpy; interfacial solar evaporation, molybdenum nitrides; reduced graphene oxides |
Description: | Published online: March 14, 2023 |
Rights: | © 2023 The Authors. Advanced Functional Materials published by Wiley- VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution-NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. |
DOI: | 10.1002/adfm.202214828 |
Grant ID: | http://purl.org/au-research/grants/arc/FT190100485 http://purl.org/au-research/grants/arc/DP220100583 |
Published version: | http://dx.doi.org/10.1002/adfm.202214828 |
Appears in Collections: | Chemical Engineering publications |
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hdl_139944.pdf | Published version | 8.5 MB | Adobe PDF | View/Open |
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