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dc.contributor.authorGrundler, Pascal Vincenten
dc.contributor.authorLaurenczy, Gaboren
dc.contributor.authorMerbach, Andre E.en
dc.identifier.citationHelvetica Chimica Acta, 2001; 84 (10):2854-2867en
dc.description.abstractSince the first facile synthesis of [Ru(H2O)6](tos)2 was published at the beginning of the eighties, several RuII aqueous inorganic and organometallic complexes were described, showing the increasing interest in this kind of compound due to potential applications in catalysis and medicine. To understand what governs the reactivity of the ligands in the first coordination sphere of the RuII center, we discuss its solution behavior, starting with the simplest aqueous species [Ru(H2O)6]2+ and moving progressively in complexity with selected examples. In addition, we present variable-pressure measurements with two objectives: to determine activation volumes for mechanistic assignments, and to shift equilibria by increasing the solubility of gaseous molecules.en
dc.description.statementofresponsibilityPascal V. Grundler, Gabor Laurenczy, André E. Merbachen
dc.publisherVerlag Helvetica Chimica Actaen
dc.rightsCopyright © 2001 Neue Schweizerische Chemische Gesellschaften
dc.titleAspects of Aqueous Ruthenium(II) Chemistryen
dc.typeJournal articleen
dc.contributor.schoolSchool of Earth and Environmental Sciences : Geology and Geophysicsen
Appears in Collections:Earth and Environmental Sciences publications

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