Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/39201
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Maselli, O. | - |
dc.contributor.author | Gascooke, J. | - |
dc.contributor.author | Kobelt, S. | - |
dc.contributor.author | Metha, G. | - |
dc.contributor.author | Buntine, M. | - |
dc.date.issued | 2006 | - |
dc.identifier.citation | Australian Journal of Chemistry: an international journal for chemical science, 2006; 59(2):104-108 | - |
dc.identifier.issn | 0004-9425 | - |
dc.identifier.issn | 1445-0038 | - |
dc.identifier.uri | http://hdl.handle.net/2440/39201 | - |
dc.description | Copyright © 2006 CSIRO | - |
dc.description.abstract | We have measured the rotational energy distribution of benzene molecules both evaporated and desorbed by an IR laser from a liquid microjet. Analysis of the 6₀¹ vibronic band of benzene has shown that the benzene molecules evaporating from the liquid microjet surface have a rotational temperature of 157 ± 7 K. In contrast, the rotational temperature of benzene molecules desorbed from the liquid microjet by a 1.9 μm laser pulse is 82 ± 5 K. However, in both cases careful inspection of the spectral profiles shows that the experimental rotational distributions are non-Boltzmann, displaying an underpopulation of high rotational states and a relative overpopulation of the low rotational states. The non-equilibrium evaporation and desorption spectral profiles are consistent with a model that involves transfer of internal energy into translation upon liberation from the condensed phase. | - |
dc.description.statementofresponsibility | Olivia J. Maselli, Jason R. Gascooke, Sarah L. Kobelt, Gregory F. Metha and Mark A. Buntine | - |
dc.language.iso | en | - |
dc.publisher | C S I R O Publishing | - |
dc.source.uri | http://www.publish.csiro.au/nid/51/paper/CH05319.htm | - |
dc.title | Rotational Energy Distributions of Benzene Liberated from Aqueous Liquid Microjets: A Comparison between Evaporation and Infrared Desorption | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1071/CH05319 | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Metha, G. [0000-0003-1094-0947] | - |
Appears in Collections: | Aurora harvest Chemistry publications Environment Institute publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.