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https://hdl.handle.net/2440/4584
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Type: | Journal article |
Title: | Dinuclear organoplatinum (II)-methyldiphenylphosphine complexes of nicotinic acid |
Author: | Crisp, M. Pyke, S. Rendina, L. |
Citation: | Journal of Organometallic Chemistry, 2000; 607(1-2):222-226 |
Publisher: | Elsevier Science Sa |
Issue Date: | 2000 |
ISSN: | 0022-328X 1872-8561 |
Statement of Responsibility: | Michael G. Crisp, Simon M. Pyke, Louis M. Rendina |
Abstract: | The preparation and characterisation of a series of novel, dinuclear organoplatinum(II) complexes of methyldiphenylphosphine, trans-[Pt(PMePh2)2(C5H4N(CO 2H))-μ-aryl-Pt(PMePh2)2(C5H 4N(CO2H))](OTf)2 (aryl = phenyl, 4,4′-biphenyl, 4,4″-p-terphenyl, or 4,4′-benzophenone; OTf = triflate), in which nicotinic acid acts a nitrogen-donor ligand are described. The key structural feature of each complex is the presence of a carboxylic acid group at each end of the molecule. This allows for their association via intermolecular hydrogen-bonds in low polarity solvents. The complexes are potentially useful tectons (building blocks) for the construction of metal-containing supramolecular assemblies. © 2000 Published by Elsevier Science S.A. All rights reserved. |
Keywords: | Dinuclear platinum complex Hydrogen-bonding Tecton Nicotinic acid Methyldiphenylphosphine |
Rights: | © 2000 Elsevier Science S.A. All rights reserved. |
DOI: | 10.1016/S0022-328X(00)00375-2 |
Description (link): | http://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description |
Published version: | http://dx.doi.org/10.1016/s0022-328x(00)00375-2 |
Appears in Collections: | Aurora harvest 6 Chemistry publications |
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