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Type: Journal article
Title: Some neutral ruthenium complexes and a novel 1,3-elimination reaction reaction: Preparation of some chiral ruthenium acetylides
Author: Bruce, M.
Hall, B.
Zaitseva, N.
Skelton, B.
White, A.
Citation: Journal of Organometallic Chemistry, 1996; 522(2):307-310
Publisher: Elsevier BV
Issue Date: 1996
ISSN: 0022-328X
Statement of
Michael I. Bruce, Ben C. Hall, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White
Abstract: Reactions of RuCl(PPh3)2Cp* with 1-alkynes in non-polar solvents afford the neutral vinylidene complexes RuCl(C=CHR)(PPh3) Cp* [R=Ph (X-ray structure), Bu1, SiMe3, CO2Me]; a novel 1,3 elimination of HCl induced by NaOMe in the presence of a variety of ligands gives the chiral-at-metal complexes Ru(Ctriple bond; length as m-dashCR)(L)(PPh3)Cp* [L=CO, C2H4 (X-ray structure), PR3, P(OR)3, O2, S2, CS2 (for example)].
Keywords: Crystal structure
Rights: Copyright © 1996 Published by Elsevier Science B.V.
DOI: 10.1016/0022-328X(96)06200-6
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Chemistry publications

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