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https://hdl.handle.net/2440/4671
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Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Bruce, M. | - |
dc.contributor.author | Skelton, B. | - |
dc.contributor.author | White, A. | - |
dc.contributor.author | Zaitseva, N. | - |
dc.date.issued | 2000 | - |
dc.identifier.citation | Dalton Transactions: an international journal of inorganic chemistry, 2000; 2000(6):881-890 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.issn | 0300-9246 | - |
dc.identifier.uri | http://hdl.handle.net/2440/4671 | - |
dc.description | © Royal Society of Chemistry 2000 | - |
dc.description.abstract | The chemistry of some ruthenium cluster carbonyls containing allenylidene ligands has been reinvestigated. Treatment of Ru₃(μ-H){μ₃-C₂CAr₂(OH)}(CO)₉ [Ar = Ph 15, tol (tol = 4-MeC₆H₄)] with HBF₄•OMe₂ gave Ru₃(μ-H)(μ₃-CCCAr₂)(CO)₉ (Ar = Ph, R = H, Me; Ar = tol, R = H). Substitution of CO by PPh₃ or dppm gave Ru₃(μ-H)(μ₃-CCCPh₂)(μ-OH)(CO)₇(L)₂ (L = PPh₃, L₂ = dppm; from 15), while in the presence of HBF₄, the hydroxy-free complexes Ru₃(μ₃-CCCAr₂)(μ-dppm)(μ-CO)(CO)₇ were obtained. Reactions of 15 with K[BHBus ₃], followed by HBF₄ or AuCl(PPh₃), also resulted in loss of water to give Ru₃(μ-H)(μ-E)(μ₃-CCCPh₂)(CO) ₉ [E = H or Au(PPh₃), respectively]. X-Ray structures of six of the complexes are reported. | - |
dc.description.statementofresponsibility | Michael I. Bruce, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva | - |
dc.language.iso | en | - |
dc.publisher | Royal Soc Chemistry | - |
dc.source.uri | http://www.rsc.org/Publishing/Journals/DT/article.asp?doi=a906379j | - |
dc.title | Preparation and structural characterisation of some ruthenium cluster carbonyls containing allenylidene ligands | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1039/a906379j | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Bruce, M. [0000-0002-8377-7186] | - |
Appears in Collections: | Aurora harvest 2 Chemistry publications |
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