Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/47526
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Type: | Journal article |
Title: | Diphenylphosphinoyl chloride as a chlorinating agent - The selective double activation of 1,2-diols |
Author: | Fox, David J. Pedersen, Daniel Sejer Petersen, Asger B. Warren, Stuart |
Citation: | Organic and Biomolecular Chemistry , 2006; 4 (16):3117-3119 |
Publisher: | Royal Society Chemistry |
Issue Date: | 2006 |
ISSN: | 1477-0520 |
School/Discipline: | School of Chemistry and Physics : Chemistry |
Statement of Responsibility: | David J. Fox, Daniel Sejer Pedersen, Asger B. Petersen and Stuart Warren |
Abstract: | Treatment of 1,2-diols with diphenylphosphinoyl chloride in pyridine produces beta-chloroethyl phosphinates which react with complete control of stereochemistry to give epoxides and azido-alcohols, useful intermediates in cyclopropane synthesis. |
Description: | © The Royal Society of Chemistry 2006 |
DOI: | 10.1039/b606881b |
Appears in Collections: | Chemistry and Physics publications |
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hdl_47526.pdf | 139.38 kB | Publisher's PDF | View/Open |
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