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https://hdl.handle.net/2440/4808
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Type: | Journal article |
Title: | Synthesis, Characterization and X-ray Structures of Diphenyltin(IV) N-(2-Hydroxyacetophenone)glycinate, Its 1:1 Adduct with Triphenyltin(IV) Chloride, and Related Systems |
Author: | Dakternieks, Dainis Basu Baul, Tushar S. Dutta, Sushmita Tiekink, Edward Richard Tom |
Citation: | Organometallics, 1998; 17(14):3058-3062 |
Issue Date: | 1998 |
ISSN: | 0276-7333 |
School/Discipline: | School of Chemistry and Physics |
Statement of Responsibility: | Dainis Dakternieks, Tushar S. Basu Baul, Sushmita Dutta and Edward R. T. Tiekink |
Abstract: | The compound [Ph2Sn(2-OC6H4C(CH3)NCH2COO)], 1, shows a distorted trigonal-bipyramidal geometry in the solid state. Reaction of 1 with Ph3SnCl yields a 1:1 adduct in which the two tin atoms are joined via the carbonyl atom of the ligand in 1 to form a mixed diorgano/triorgano species. NMR data indicate that the 1:1 adduct dissociates in noncoordinating solvent. Similarly, [tBu2Sn(2-OC6H4C(CH3)NCH2COO)·tBu2SnCl2], which has been characterized crystallographically in the solid state, is dissociated in solution. In contrast to the above behavior, monomeric [Vin2Sn(2-OC6H4C(CH3)NCH2COO)] forms an adduct with a water molecule to yield [Vin2Sn(2-OC6H4C(CH3)NCH2COO)OH2] in the solid state. |
Description: | Copyright © 1998 American Chemical Society |
DOI: | 10.1021/om9800290 |
Appears in Collections: | Chemistry publications |
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