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Type: Journal article
Title: Hydroxyselenation of allylic alcohols
Author: Cooper, M.
Ward, A.
Citation: Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry, 1995; 36(13):2327-2330
Publisher: Pergamon
Issue Date: 1995
ISSN: 0040-4039
Abstract: Hydroxyselenation of terminal or cyclic allylic alcohols occurs with high regio- and stereoselectivity to give β,β′-dihydroxyphenylselenated adducts in high yields. A mechanism for this selectivity is proposed. The utility of these adducts is illustrated by the conversion of the hydroxyselenide (9a) to the epoxide (11) via the intermediacy of a selenone. © 1995.
DOI: 10.1016/0040-4039(95)00247-A
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