Adelaide Research & Scholarship
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https://hdl.handle.net/2440/4899
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| Type: | Journal article |
| Title: | Hydroxyselenation of allylic alcohols |
| Author: | Cooper, M. Ward, A. |
| Citation: | Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry, 1995; 36(13):2327-2330 |
| Publisher: | Pergamon |
| Issue Date: | 1995 |
| ISSN: | 0040-4039 |
| Abstract: | Hydroxyselenation of terminal or cyclic allylic alcohols occurs with high regio- and stereoselectivity to give β,β′-dihydroxyphenylselenated adducts in high yields. A mechanism for this selectivity is proposed. The utility of these adducts is illustrated by the conversion of the hydroxyselenide (9a) to the epoxide (11) via the intermediacy of a selenone. © 1995. |
| DOI: | 10.1016/0040-4039(95)00247-A |
| Published version: | http://dx.doi.org/10.1016/0040-4039(95)00247-a |
| Appears in Collections: | Aurora harvest 6 Chemistry publications |
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