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https://hdl.handle.net/2440/49062
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Type: | Journal article |
Title: | Iodo-alkynyl- and iodo-butadiynyl-ruthenium complexes |
Author: | Bruce, M. Jevric, M. Parker, C. Patalinghug, W. Skelton, B. White, A. Zaitseva, N. |
Citation: | Journal of Organometallic Chemistry, 2008; 693(17):2915-2920 |
Publisher: | Elsevier Science Sa |
Issue Date: | 2008 |
ISSN: | 0022-328X 1872-8561 |
Statement of Responsibility: | Michael I. Bruce, Martyn Jevric, Christian R. Parker, Wyona Patalinghug, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva |
Abstract: | Addition of [I(py)2]BF4 to Ru(Ctriple bond; length of mdashCH)(dppe)Cp* gave the iodovinylidene [Ru(double bond; length as m-dashCdouble bond; length as m-dashCHI)(dppe)Cp*]BF4 1, which could be deprotonated to Ru(Ctriple bond; length of mdashCI)(dppe)Cp* 2. The attempted preparation of Ru(Ctriple bond; length of mdashCCtriple bond; length of mdashCI)(dppe)Cp*, followed by derivatisation with tcne, gave the dienynyl Ru{Ctriple bond; length of mdashCC[double bond; length as m-dashC(CN)2]CIdouble bond; length as m-dashC(CN)2}(dppe)Cp* 3. The Pd(0)/Cu(I)-catalysed reaction of 3 with Ru{Ctriple bond; length of mdashCCtriple bond; length of mdashCAu(PPh3)}(dppe)Cp* afforded Ru{Ctriple bond; length of mdashCCdouble bond; length as m-dashC(CN)2Cdouble bond; length as m-dashC(CN)2Au(PPh3)}(dppe)Cp* 4 by formal replacement of I+ by [Au(PPh3)]+. XRD structures of 1–4 are reported. |
Keywords: | Diynyl Gold Iodo-alkynyl Ruthenium Tetracyanoethene XRD structure |
Description: | Copyright © 2008 Elsevier B.V. |
DOI: | 10.1016/j.jorganchem.2008.06.008 |
Description (link): | http://www.sciencedirect.com/science/journal/0022328X http://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#description |
Published version: | http://dx.doi.org/10.1016/j.jorganchem.2008.06.008 |
Appears in Collections: | Aurora harvest 5 Chemistry and Physics publications |
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