Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/51363
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Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Robinson, T. | - |
dc.contributor.author | Pedersen, D. | - |
dc.contributor.author | Taylor, D. | - |
dc.contributor.author | Tiekink, E. | - |
dc.date.issued | 2009 | - |
dc.identifier.citation | Journal of Organic Chemistry, 2009; 74(14):5093-5096 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.issn | 1520-6904 | - |
dc.identifier.uri | http://hdl.handle.net/2440/51363 | - |
dc.description | Copyright © 2009 American Chemical Society | - |
dc.description.abstract | The synthesis of 2-C-branched erythritol derivatives, including the plant sugar (+/-)-2-C-methylerythritol 2, was achieved through a dihydroxylation/reduction sequence on a series of 4-substituted 1,2-dioxines 3. The asymmetric dihydroxylation of 1,2-dioxines was examined, providing access to optically enriched dihydroxy 1,2-dioxanes 4. The synthesized 1,2-dioxanes were converted to other erythro sugar analogues and tetrahydrofurans through controlled cleavage of the endoperoxide linkage. | - |
dc.description.statementofresponsibility | Tony V. Robinson, Daniel Sejer Pedersen, Dennis K. Taylor and Edward R. T. Tiekink | - |
dc.language.iso | en | - |
dc.publisher | Amer Chemical Soc | - |
dc.source.uri | http://dx.doi.org/10.1021/jo900669u | - |
dc.subject | Erythritol | - |
dc.subject | Dioxins | - |
dc.subject | Carbohydrates | - |
dc.subject | Molecular Structure | - |
dc.subject | Oxidation-Reduction | - |
dc.subject | Hydroxylation | - |
dc.subject | Stereoisomerism | - |
dc.title | Dihydroxylation of 4-substituted 1,2-dioxines: A concise route to branched erythro sugars | - |
dc.type | Journal article | - |
dc.identifier.doi | 10.1021/jo900669u | - |
pubs.publication-status | Published | - |
dc.identifier.orcid | Taylor, D. [0000-0002-3302-4610] [0000-0002-4274-3983] [0000-0003-0633-7424] | - |
Appears in Collections: | Aurora harvest 5 Chemistry and Physics publications |
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