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https://hdl.handle.net/2440/51872
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Type: | Journal article |
Title: | Sodium pentafluorobenzoate monohydrate: A novel two-dimensional carboxylate polymer with strong sodium-fluorine interactions |
Author: | Bruce, M. Hall, B. Skelton, B. White, A. |
Citation: | Zeitschrift fuer Anorganische und Allgemeine Chemie, 2008; 634(6-7):1111-1114 |
Publisher: | Wiley-V C H Verlag GMBH |
Issue Date: | 2008 |
ISSN: | 0044-2313 1521-3749 |
Statement of Responsibility: | Michael I. Bruce, Benjamin C. Hall, Brian W. Skelton, and Allan H. White |
Abstract: | <jats:title>Abstract</jats:title><jats:p>Sodium pentafluorobenzoate monohydrate, Na<jats:sup>+</jats:sup>[C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>CO<jats:sub>2</jats:sub>]<jats:sup>−</jats:sup>·H<jats:sub>2</jats:sub>O crystallizes with two such formula units in the asymmetric unit of a monoclinic <jats:italic>P</jats:italic>2<jats:sub>1</jats:sub> lattice. It forms a novel two‐dimensional array based on Na<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> rhombs, which combine sequentially in one dimension to generate a ‘cubanoid stair’ structure, in the network of which ‘chair’, ‘open cubane’, and other derivative motives may be discerned, and in which unusual Na···F interactions feature.</jats:p> |
Keywords: | Sodium Pentafluorobenzoate Polymers Network structure Hydrates |
Description: | Article first published online: 5 MAY 2008 |
Rights: | Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
DOI: | 10.1002/zaac.200800023 |
Published version: | http://dx.doi.org/10.1002/zaac.200800023 |
Appears in Collections: | Aurora harvest Chemistry publications |
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