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Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/55138
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dc.contributor.authorKhairul, W.-
dc.contributor.authorFox, M.-
dc.contributor.authorZaitseva, N.-
dc.contributor.authorGaudio, M.-
dc.contributor.authorYufit, D.-
dc.contributor.authorSkelton, B.-
dc.contributor.authorWhite, A.-
dc.contributor.authorHoward, J.-
dc.contributor.authorBruce, M.-
dc.contributor.authorLow, P.-
dc.date.issued2009-
dc.identifier.citationDalton Transactions: an international journal of inorganic chemistry, 2009; 2009(4):610-620-
dc.identifier.issn1477-9226-
dc.identifier.issn1477-9234-
dc.identifier.urihttp://hdl.handle.net/2440/55138-
dc.description.abstractFacile acetylide transfer reactions take place between gold(I) complexes Au(C[triple bond]CAr)(PPh3) (Ar = C6H5 or C6H4Me-4) and a variety of representative inorganic and organometallic complexes MXL, (M = metal, X = halide, L, = supporting ligands) featuring metals from groups 8-11, to afford the corresponding metal-alkynyl complexes M(C[triple bond]CR)Ln in modest to good yield. Reaction products have been characterised by spectroscopic methods, and molecular structure determinations are reported for Fe(C[triple bond]CC6H4Me-4)(dppe)Cp, Ru(C[triple bond]CC6H4Me-4)(dppe)Cp*, Ru(C=CCsF,)(l2-O2)(PPh3)Cp*, Ir(C-CC6H4Me-4)(eta2-O2)(CO)(PPh3), Ni(C[triple bond]CC6H4Me-4)(PPh3)Cp and trans-Pt(C[triple bond]CAr)2L2 (Ar = C6H5, L = PPh3; Ar = C6H4Me-4, L = PPh3, PMe3).-
dc.description.statementofresponsibilityWan M. Khairul, Mark A. Fox, Natasha N. Zaitseva, Maryka Gaudio, Dmitry S. Yufit, Brian W. Skelton, Allan H. White, Judith A. K. Howard, Michael I. Bruce and Paul J. Low-
dc.language.isoen-
dc.publisherRoyal Soc Chemistry-
dc.source.urihttp://dx.doi.org/10.1039/b809960j-
dc.titleTransition metal alkynyl complexes by transmetallation from Au(C CAr)(PPh3) (Ar = C6H5 or C6H4Me-4)-
dc.typeJournal article-
dc.identifier.doi10.1039/b809960j-
pubs.publication-statusPublished-
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]-
Appears in Collections:Aurora harvest 5
Chemistry and Physics publications

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