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https://hdl.handle.net/2440/60047
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Type: | Journal article |
Title: | Formation of an acyl-ethynyl-methylidyne complex of cobalt: structure of Co₃{μ₃-CC(O)C≡C [Ru(dppe)Cp*]} (CO)₈(PPh₃) |
Other Titles: | Formation of an acyl-ethynyl-methylidyne complex of cobalt: structure of Co(3){mu(3)-CC(O)Ctriple barC [Ru(dppe)Cp*]} (CO)(8)(PPh(3)) |
Author: | Bruce, M. Zaitseva, N. Skelton, B. White, A. |
Citation: | Zeitschrift fuer Anorganische und Allgemeine Chemie, 2010; 636(6):1075-1077 |
Publisher: | Wiley-V C H Verlag GMBH |
Issue Date: | 2010 |
ISSN: | 0044-2313 1521-3749 |
Statement of Responsibility: | Michael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White |
Abstract: | The reaction between Ru(C≡CH)(dppe)Cp* and Co3(μ3-CBr)(CO)9 in the presence of Pd(PPh3)4/CuI afforded dark red Co3{μ3-CC(O)C≡C[Ru(dppe)Cp*]}(CO)8(PPh3), whose formation may involve attack of the Ru-ethynyl fragment on an intermediate clusterbound CCO ligand; abstraction of PPh3 from the palladium catalyst also occurs. |
Keywords: | Cobalt Ruthenium Cluster compounds Crystal structure Acyl-ethynyl complex |
Rights: | Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
DOI: | 10.1002/zaac.200900535 |
Grant ID: | ARC |
Published version: | http://dx.doi.org/10.1002/zaac.200900535 |
Appears in Collections: | Aurora harvest 5 Chemistry publications |
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