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Type: Journal article
Title: Structural reassignment of Cytosporolides A - C via biomimetic synthetic studies and reinterpretation of NMR data
Author: Spence, J.
George, J.
Citation: Organic Letters, 2011; 13(19):5318-5321
Publisher: Amer Chemical Soc
Issue Date: 2011
ISSN: 1523-7060
Statement of
Justin T. J. Spence and Jonathan H. George
Abstract: A structure revision for the recently isolated fungal meroterpenoids, cytosporolides A-C, is suggested based on biosynthetic speculation and reinterpretation of existing spectroscopic data. The structure revision is supported by a biomimetic synthetic study, featuring a [4 + 2] cycloaddition reaction between a presumed o-quinone methide intermediate and β-caryophyllene.
Keywords: Sesquiterpenes; Magnetic Resonance Spectroscopy; Molecular Structure; Cyclization; Biomimetic Materials; Polycyclic Sesquiterpenes
Rights: © 2011 American Chemical Society
RMID: 0020112553
DOI: 10.1021/ol202181g
Appears in Collections:Chemistry publications

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