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https://hdl.handle.net/2440/71105
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Type: | Journal article |
Title: | Syntheses and structural studies of several diynyl-ruthenium complexes and their adducts with cyano-alkenes |
Author: | Bruce, M. Burgun, A. Grelaud, G. Jevric, M. Nicholson, B. Skelton, B. White, A. Zaitseva, N. |
Citation: | Zeitschrift fuer Anorganische und Allgemeine Chemie, 2011; 637(10):1334-1340 |
Publisher: | Wiley-V C H Verlag GMBH |
Issue Date: | 2011 |
ISSN: | 0044-2313 1521-3749 |
Statement of Responsibility: | Michael I. Bruce, Alexandre Burgun, Guillaume Grelaud, Martyn Jevric, Brian K. Nicholson, Brian W. Skelton, Allan H. White, and Natasha N. Zaitseva |
Abstract: | <jats:title>Abstract</jats:title><jats:p>Herein are described some continuing investigations into the reactions of cyano‐alkenes with diynyl‐ruthenium complexes which have resulted in the preparation and characterisation of diynyl‐ruthenium compounds Ru(C≡CC≡C<jats:italic>R</jats:italic>)(PP)Cp [<jats:italic>R</jats:italic> = Ph, PP = dppe; <jats:italic>R</jats:italic> = Fc, PP = dppf; <jats:italic>R</jats:italic> = CPh=CBr<jats:sub>2</jats:sub>, PP = (PPh<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>], together with the polycyanobutadienyls Ru{C≡CC[=C(CN)<jats:sub>2</jats:sub>]C<jats:italic>R</jats:italic>=C<jats:italic>R</jats:italic>′(CN)}(PP)Cp′ [<jats:italic>R</jats:italic> = Fc, (PP)Cp′ = (dppf)Cp; <jats:italic>R</jats:italic> = H, SiMe<jats:sub>3</jats:sub>, (PP)Cp′ = (dppe)Cp*] formed by [2 + 2]‐cycloaddition of the cyano‐alkenes to the outer C≡C triple bonds and subsequent ring‐opening reactions. Single‐crystal XRD molecular structure determinations of six complexes are reported.</jats:p> |
Keywords: | Ruthenium Diinyl Cyanocarbon X-ray diffraction Alkenes |
Rights: | © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
DOI: | 10.1002/zaac.201100123 |
Grant ID: | ARC |
Published version: | http://dx.doi.org/10.1002/zaac.201100123 |
Appears in Collections: | Aurora harvest Chemistry publications |
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