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Type: Journal article
Title: Pentamethylcyclopentadienyl(η6-cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6-C8H10)]2ZnCl4
Other Titles: Pentamethylcyclopentadienyl(eta6-cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(eta6-C8H10)]2ZnCl4
Author: Bruce, M.
Joly, D.
Skelton, B.
White, A.
Citation: Zeitschrift fuer Anorganische und Allgemeine Chemie, 2011; 637(6):641-642
Publisher: Wiley-V C H Verlag GMBH
Issue Date: 2011
ISSN: 0044-2313
Statement of
Michael I. Bruce, Damien Joly, Brian W. Skelton, and Allan H. White
Abstract: The crystal and molecular structures of the title compound, the first for a complex of the type [RuCp*(η6-C8-ring)]+, is presented, the material being obtained serendipitously from a reaction between RuCl(cod)Cp* and 1-ferrocenylbuta-1,3-diyne in the presence of ZnCl2. <Ru-C(Cp*)> (2.21 Å) is appreciably longer than in RuCp*2 (2.18 Å) and similar to the value for the Ru-η6 component (2.22 Å).
Keywords: Ruthenium
Description: Article first published online: 25 MAR 2011
Rights: © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
DOI: 10.1002/zaac.201000447
Grant ID: ARC
Published version:
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Chemistry and Physics publications

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