Adelaide Research & Scholarship
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https://hdl.handle.net/2440/71192
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| Type: | Journal article |
| Title: | Pentamethylcyclopentadienyl(η6-cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(η6-C8H10)]2ZnCl4 |
| Other Titles: | Pentamethylcyclopentadienyl(eta6-cyclooctatrienyl)ruthenium Tetrachlorozincate, [RuCp*(eta6-C8H10)]2ZnCl4 |
| Author: | Bruce, M. Joly, D. Skelton, B. White, A. |
| Citation: | Zeitschrift fuer Anorganische und Allgemeine Chemie, 2011; 637(6):641-642 |
| Publisher: | Wiley-V C H Verlag GMBH |
| Issue Date: | 2011 |
| ISSN: | 0044-2313 1521-3749 |
| Statement of Responsibility: | Michael I. Bruce, Damien Joly, Brian W. Skelton, and Allan H. White |
| Abstract: | The crystal and molecular structures of the title compound, the first for a complex of the type [RuCp*(η6-C8-ring)]+, is presented, the material being obtained serendipitously from a reaction between RuCl(cod)Cp* and 1-ferrocenylbuta-1,3-diyne in the presence of ZnCl2. <Ru-C(Cp*)> (2.21 Å) is appreciably longer than in RuCp*2 (2.18 Å) and similar to the value for the Ru-η6 component (2.22 Å). |
| Keywords: | Ruthenium Cyclopentadienyl Cyclooctatrienyl Zinc |
| Description: | Article first published online: 25 MAR 2011 |
| Rights: | © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
| DOI: | 10.1002/zaac.201000447 |
| Grant ID: | ARC |
| Published version: | http://dx.doi.org/10.1002/zaac.201000447 |
| Appears in Collections: | Aurora harvest Chemistry and Physics publications |
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