Adelaide Research & Scholarship
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https://hdl.handle.net/2440/74109
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| Type: | Journal article |
| Title: | A ruthenated [3]dendralene from phenylethyne and an η³-butadienyl–ruthenium complex |
| Other Titles: | A ruthenated [3]dendralene from phenylethyne and an eta3- butadienyl-ruthenium complex |
| Author: | Bruce, M. Skelton, B. Zaitseva, N. |
| Citation: | Organometallics, 2012; 31(14):5034-5038 |
| Publisher: | Amer Chemical Soc |
| Issue Date: | 2012 |
| ISSN: | 0276-7333 1520-6041 |
| Statement of Responsibility: | Michael I. Bruce, Brian W. Skelton, and Natasha N. Zaitseva |
| Abstract: | The reaction of HC≡CPh with Ru{η 3-C(CN) 2CPhC=C(CN) 2}(PPh 3)Cp (1) affords as one product the metalated [3]dendralene Ru{CPh=CHC[=C(CN) 2]CPh=C(CN) 2}{NC[Ru(PPh 3) 2Cp]}Cp (2), in which a molecule of Ru(CN)(PPh 3) 2Cp is also coordinated via the CN nitrogen to the Ru center, as shown by a single-crystal X-ray structural determination. © 2012 American Chemical Society. |
| Rights: | © 2012 American Chemical Society |
| DOI: | 10.1021/om300366g |
| Grant ID: | ARC |
| Published version: | http://dx.doi.org/10.1021/om300366g |
| Appears in Collections: | Aurora harvest 4 Chemistry publications |
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