Adelaide Research & Scholarship
Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/74823
| Citations | ||
| Scopus | Web of Science® | Altmetric |
|---|---|---|
|
?
|
?
|
|
| Type: | Journal article |
| Title: | Biomimetic total synthesis of (±)-garcibracteatone |
| Other Titles: | Biomimetic total synthesis of (+/-)-garcibracteatone |
| Author: | Pepper, H. Lam, H. Bloch, W. George, J. |
| Citation: | Organic Letters, 2012; 14(19):5162-5164 |
| Publisher: | Amer Chemical Soc |
| Issue Date: | 2012 |
| ISSN: | 1523-7060 1523-7052 |
| Statement of Responsibility: | Henry P. Pepper, Hiu C. Lam, Witold M. Bloch, and Jonathan H. George |
| Abstract: | The polycyclic polyprenylated acylphloroglucinol natural product garcibracteatone has been synthesized in four steps from phloroglucinol, using a strategy based on biosynthetic speculation. The key biomimetic transformation is a cascade of 7-endo-trig and 5-exo-trig radical cyclizations followed by a terminating aromatic substitution reaction. |
| Keywords: | Polycyclic Compounds Molecular Structure Models, Molecular Biomimetic Materials |
| Rights: | Copyright © 2012 American Chemical Society |
| DOI: | 10.1021/ol302524q |
| Published version: | http://dx.doi.org/10.1021/ol302524q |
| Appears in Collections: | Aurora harvest 4 Chemistry publications IPAS publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.