Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/79477
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Using hinged ligands to target structurally flexible copper(II) MOFs |
Author: | Bloch, W. Doonan, C. Sumby, C. |
Citation: | CrystEngComm, 2013; 15(45):9663-9671 |
Publisher: | Royal Society of Chemistry |
Issue Date: | 2013 |
ISSN: | 1466-8033 1466-8033 |
Statement of Responsibility: | Witold M. Bloch, Christian J. Doonan and Christopher J. Sumby |
Abstract: | Here we report two new flexible MOFs based on a bis-pyrazolylmethane 'hinged' link design that favours the formation of two distinct structural nodes within the resulting 2-D and 3-D structures. The less sterically demanding ligand H₂bcppm affords a 2-D layered MOF, {Cu₂[Cuˡˡ(NO₃)₂(bcppm)₂](DMF)₂}•2DMF (1), constructed from copper(II) paddlewheel and mononuclear octahedral copper(II) nodes. The use of a more sterically encumbered tetramethyl analogue H₂bcpdmpm induces a dramatic twisting of the ligand backbone that yields a 3-D MOF{Cu₄[Cuˡ(bcpdmpm)₂]₂(EtOH)₂(H₂O)₂}(NO₃)₂•12DMF (2) formed from a very similar mix of nodes, specifically copper(II) paddlewheel clusters and mononuclear tetrahedrally coordinated copper(I) centres. Herein we describe the crystal structures, solid-state flexibility, and gas adsorption properties of both materials. |
Description: | First published online 23 Aug 2013 |
Rights: | © The Royal Society of Chemistry 2013 |
DOI: | 10.1039/C3CE41244J |
Grant ID: | http://purl.org/au-research/grants/arc/FT100100400 http://purl.org/au-research/grants/arc/FT0991910 |
Published version: | http://dx.doi.org/10.1039/c3ce41244j |
Appears in Collections: | Aurora harvest 4 Chemistry and Physics publications Environment Institute publications |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
hdl_79477.pdf | Published version | 1.29 MB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.