Adelaide Research & Scholarship
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https://hdl.handle.net/2440/91252
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| Type: | Book chapter |
| Title: | Di(carbido)tetracosa(carbonyl)decaruthenate(2–) Salts |
| Author: | Bruce, M. Castro, A. Humphrey, P. Maitlis, P. Zaitseva, N. Viau, L. Humphrey, M. |
| Citation: | Inorganic Syntheses, 2014 / Girolami, G, , Sattelberger, A. (ed./s), vol.36, Ch.23, pp.126-128 |
| Publisher: | John Wiley & Sons |
| Publisher Place: | United States |
| Issue Date: | 2014 |
| ISBN: | 9781118744871 |
| Editor: | Girolami, G, Sattelberger, A. |
| Statement of Responsibility: | Michael L. Bruce, Aurora Castro, Paul A. Humphrey, Peter M. Maitlis, Natasha N. Zaitseva, Lydie Viau and Mark G. Humphrey |
| Abstract: | For the metal ruthenium, many examples of clusters with different nuclearity are known. The Ru10C2 cluster is formed by edge sharing of two Ru6C clusters. This chapter describes a synthesis of the decanuclear anion [Ru10C2(CO)24]2- from Ru3(CO)12 and calcium carbide in up to 50% yield. The chapter discusses the procedures and properties of calcium di(carbido)tetracosa(carbonyl) decaruthenium(2-) and BIS(triphenylphosphoranylidene)ammonium di (carbido)tetracosa(carbonyl)decaruthenium(2-). |
| Keywords: | calcium di(carbido)tetracosa(carbonyl) decaruthenium(2-); di(Carbido)tetracosa(Carbonyl) decaruthenium(2-) salts; ruthenium |
| Description: | Published Online: 11 APR 2014 |
| Rights: | © 2014 John Wiley & Sons, Inc. |
| DOI: | 10.1002/9781118744994.ch23 |
| Published version: | http://dx.doi.org/10.1002/9781118744994.ch23 |
| Appears in Collections: | Aurora harvest 2 Chemistry and Physics publications |
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