Please use this identifier to cite or link to this item: https://hdl.handle.net/2440/96413
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dc.contributor.authorTeo, J.-
dc.contributor.authorCoghlan, C.-
dc.contributor.authorEvans, J.-
dc.contributor.authorTsivion, E.-
dc.contributor.authorHead-Gordon, M.-
dc.contributor.authorSumby, C.-
dc.contributor.authorDoonan, C.-
dc.date.issued2016-
dc.identifier.citationChemical Communications, 2016; 52(2):276-279-
dc.identifier.issn1364-548X-
dc.identifier.issn1364-548X-
dc.identifier.urihttp://hdl.handle.net/2440/96413-
dc.descriptionFirst published online 26 Oct 2015-
dc.description.abstractPorous metal-organic polyhedra (MOPs), constructed from heterometallic Pd(II)-M(II) (M = Cu, Ni, Zn) paddlewheel nodes and 5-tert-butyl-1,3-benzenedicarboxylate organic links, were prepared in which the Pd(II) ions preferentially line the inner surface of the cage molecules. Careful activation produces co-ordinatively unsaturated 3d transition metal sites on the external MOP surfaces giving rise to H2 adsorption enthalpies in excess of -12 kJ mol(-1).-
dc.description.statementofresponsibilityJesse M. Teo, Campbell J. Coghlan, Jack D. Evans, Ehud Tsivion, Martin Head-Gordon, Christopher J. Sumby, and Christian J. Doonan-
dc.language.isoen-
dc.publisherRoyal Society of Chemistry-
dc.rights© the author. This journal is ©The Royal Society of Chemistry 2015.-
dc.source.urihttp://dx.doi.org/10.1039/c5cc08336b-
dc.titleHetero-bimetallic metal-organic polyhedra-
dc.typeJournal article-
dc.identifier.doi10.1039/c5cc08336b-
dc.relation.granthttp://purl.org/au-research/grants/arc/FT100100400-
dc.relation.granthttp://purl.org/au-research/grants/arc/FT0991910-
pubs.publication-statusPublished-
dc.identifier.orcidCoghlan, C. [0000-0003-1625-3216]-
dc.identifier.orcidEvans, J. [0000-0001-9521-2601]-
dc.identifier.orcidSumby, C. [0000-0002-9713-9599]-
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