Synthesis and structural characterization of some triorganotin(IV) complexes of 5-(4-chlorophenulazo)salicylic acid: Crystal and molecular structure of triphenyltin 5-(4-chlorophenylazo)salicylate 0.5C₆H₁₄
| dc.contributor.author | Basu Baul, T. | |
| dc.contributor.author | Dahr, S. | |
| dc.contributor.author | Kharbani, N. | |
| dc.contributor.author | Pyke, S. | |
| dc.contributor.author | Butcher, R. | |
| dc.contributor.author | Smith, F. | |
| dc.date.issued | 1999 | |
| dc.description.abstract | Three new triorganotin(IV) complexes, the trimethyl, tributyl and triphenyl derivatives of 5-(4-chlorophenylazo)salicylic acid, have been synthesised and characterised by <sup>1</sup>H, <sup>13</sup>C, <sup>119</sup>Sn NMR, IR and elemental analysis and the crystal structure of triphenyltin-5-(4-chlorophenylazo)salicylate is reported. The crystals are monoclinic, space group P2 <inf>1</inf>/n with a = 9.566(1) Å, b = 14.550(2)Å, c = 22.528(3)Å, β= 94.04(1), V= 3127.8(7) Å <sup>S</sup>, Z = 4 and D <inf>calc</inf> = 1.42 Mg.m <sup>-3</sup>. There is an encapsulated molecule of hexane incorporated in the structure. This complex adopts a monomeric distorted tetrahedral configuration with the ligand coordinated via a carboxylate oxygen. | |
| dc.description.statementofresponsibility | Tushar S. Basu Baul, Sushmita Dhar, Newstarland Kharbani, Simon M. Pyke, Ray Butcher, Frank E. Smith | |
| dc.identifier.citation | Main Group Metal Chemistry, 1999; 22(7):413-421 | |
| dc.identifier.doi | 10.1515/MGMC.1999.22.7.413 | |
| dc.identifier.issn | 0792-1241 | |
| dc.identifier.issn | 2191-0219 | |
| dc.identifier.orcid | Pyke, S. [0000-0002-0061-5115] | |
| dc.identifier.uri | http://hdl.handle.net/2440/4757 | |
| dc.language.iso | en | |
| dc.publisher | FREUND PUBLISHING HOUSE LTD | |
| dc.source.uri | https://doi.org/10.1515/mgmc.1999.22.7.413 | |
| dc.title | Synthesis and structural characterization of some triorganotin(IV) complexes of 5-(4-chlorophenulazo)salicylic acid: Crystal and molecular structure of triphenyltin 5-(4-chlorophenylazo)salicylate 0.5C₆H₁₄ | |
| dc.title.alternative | Synthesis and structural characterization of some triorganotin(IV) complexes of 5-(4-chlorophenulazo)salicylic acid: Crystal and molecular structure of triphenyltin 5-(4-chlorophenylazo)salicylate 0.5C(6)H(14) | |
| dc.type | Journal article | |
| pubs.publication-status | Published |